Page 1 of 8
Frontiers in Heat and Mass Transfer (FHMT), 8, 3 (2017)
DOI: 10.5098/hmt.8.3
Global Digital Central
ISSN: 2151-8629
1
NUMERICAL ANALYSIS OF NO
X PRODUCTION UNDER THE AIR
STAGED COMBUSTION
Xiangcun Qi
a
, Mo Yang
a
,
*
, Yuwen Zhang
b
a School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai, 200093
,
China
b Department of Mechanical & Aerospace Engineering, University of Missouri, Columbia, MO 65211, USA ABSTRACT
The
fo
r
m
a
t
i
o
n of thermal NO and fuel type NO emission under the air staged combustion in a tower pulverized coal fired boiler that burners are
arranged in the front and the rear wall are investigated in this paper.
Effect
s of the distribution of oxygen in the main combustion zone on NO
x
a
r
e
then analyze qualitatively. The results show that when the SOFA ratio is 34.98%, NO
x yield is
a
t the minimum; thermal NO is not only related to
temperature, but also by the influence of oxygen distribution
. When oxygen is more and the temperature is high, it is conducive to the formation of
thermal NO
.
The formation of fuel NO and the amount of oxygen and CO have a positive
c
o
r
relation, and more oxygen is conducive to the formation
of thermal NO
.
When CO is more, indicating that the reducibility is good, it will
r
e
s
u
l
t
i
n
s
i
g
n
i
fi
c
a
n
t
r
e
du
c
t
i
o
n of fuel NO
.
Based on the control of
the mount of SOFA, the distribution of oxygen in the main combustion zone must be on the rational allocation
; in the case of normal combustion, the
input of air could not be too much through the first layer burners.
Keywords: Air staged combustion; Numerical simulation; Thermal NO; Fuel NO
* Corresponding author. Email: yangm
@
usst.edu.cn
.
1. INTRODUCTION
In
t
h
e recent years, with the development of economy, people pay
more and more attention
s to energy conservation and emission
reduction
.
The NO
x is one of the main air pollutants,
a
n
d reducing
NO
x emissions has become the main research target of many scholars
worldwide
. The most common method
s
a
r
e air staged combustion,
fuel staged combustion, low oxygen combustion, flue gas
recirculation, the addition of reducing agent and so on (Cen et al.,
2004). Air staged combustion is the most common method to reduce
the NO
x
for pulverized coal fired boiler
.
Many scholars have done a lot of researches on air staged
combustion in pulverized coal fired boiler
(
Ku
a
n
g
e
t
a
l
.
,
2
0
1
1
;
M
a
e
t
a
l
.
,
2
0
1
5
;
B
a
i
e
t
a
l
.
,
2
0
1
4
;
Z
h
o
n
g
e
t
a
l
.
,
(
2
0
1
5
)
an
d Cheng et al.,
2015
)
.
The influence
s of overfire air on NO
x emission
h
a
s
b
e
e
n
a
n
a
l
y
z
e
d
, and researches show that OFA investment made the main
combustion zone be in fuel rich combustion
.
T
h
i
s is not conducive to
the formation of NO
x, and
makes the furnace exit NO
x emissions
reduction. Li et al.
(2015
) and Zhou et al.
(2011
) studied a 300MW
coal
-fired boiler and a 1000 MW
tangentially
fired
pulverized
-
coal
boiler of low NO
x combustion retrofit, which increase
s the SOFA
system, making air depth classification, can reduce the production of
NO
x
. Li et al.
(2014
) and Sun et al. (2013) focused on the tangentially
fired boiler with low nitrogen transformation and analyzed the
furnace NO
x emission characteristics. Hong et al. (2012) focused on
an o
pposed
firing
boiler
supercritical
unit and analy
zed
emission
characteristics of CO and NO
x.
A
l
l results showed that the SOFA can
effectively reduce the NO
x yield and the higher of air damper
opening degree, the smaller NO
x yield of furnace outlet.
Influences of different SOFA ratios on NO
x emission in a tower
pulverized coal fired boiler that burners are arranged in the front and
the rear wall are investigated in this paper.
F
o
r
m
a
t
i
o
n and influence
factor of thermal NO and fuel type NO emission
s are investigated
under
optimal operating conditions
.
The effect of the distribution of
oxygen in the main combustion zone on NO
x
a
r
e
a
n
a
l
y
z
e
d. It
provides a certain reference for the engineering to reduce the NO
x
emission by using the air staged combustion technology.
Fig.
1 Physical model and calculation model
14.960 m
11.455 m
18.465 m
25.015 m NO
x nozzles
12.3 m
DCB
EA
13.8 m
48.5 m
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Frontiers in Heat and Mass Transfer (FHMT), 8, 3 (2017)
DOI: 10.5098/hmt.8.3
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2. MATHEMATICAL AND PHYSICAL MODE
L
2.1 Object of
Study
The symmetric model is
u
s
u
a
l
l
y used to reduce the computational
complexity. There are a lot of papers
(Yang et al., 2014; Shen et al.,
2016) about nonlinear problems which prove the existence of
nonlinear
p
h
e
n
o
m
e
n
a. In order to improve the
v
a
l
i
d
i
t
y of the
simulation, the full scale model is used to calculate.
The object of this paper is to study a B&WB
-1025/17.5
-M type
single chamber, single steam drum, front and back wall convection
combustion of pulverized coal boiler. This model of pulverized coal
boiler is shown in Figure
1. Burners are arranged in the front and the
rear wall of the boiler. The front wall is arranged with three layers of
burners (from bottom to top are B, D and C), and the rear wall is
arranged with two layers of burners (from bottom to top are A and E),
with each layer having 4 burners; the bottom 8 burners are DRB
-
4ZTM burners, and the other 12 are AirJetTM burners. The SOFA
nozzle
s are arranged in the most upper burner of front and back wall,
with each layer has 4 SOFA nozzles (8 only), and all SOFA nozzles
are in the same elevation.
2.2 Physical
Model and
Boundary
Condition
Three
-dimensional steady
-
state model is employed to simulate the
combustion and NO
x formation in pulverized coal fired boiler. Grid is
structured hexahedral mesh, and specific division as shown in Figure
2. After grid size independent test, the total number of grids is about
2.26 million.
The air distribution of the two burners used in the boiler is
shown in Figure 3, and pulverized coal is
i
n
t
r
o
d
u
c
e
d into the furnace
through the primary air. The analysis of the boiler operating
conditions is 270MW, and the excess air coefficient is 1.20. The
pulverized coal is put into the furnace through the first layer and the
second layer burners. Third burners only input secondary air. SOFA
is input by SOFA nozzles. This boiler coal is bituminous coal, which
the element analysis and industrial analysis are shown in
Table 1. All
the nozzles of the burner are set to
b
e the velocity inlet, the outlet of
the furnace is set as the pressure outlet, and the wall surface of the
furnace is provided with no slip boundary conditions, and the
temperature of the furnace wall is 700 K (according to the
experimental results).
Table 1
The industrial analysis and element analysis Industrial analysis /% Var FCar Aar Mar
Qnet(kJ/kg)
26.93 45.39 16.30 11.38 23160 Element analysis /% Cdaf Hdaf Odaf Ndaf Sdaf
81.33 5.00 11.42 1.30 0.95
2.3
Mathematical
Model
2.3.1 Flow and
Combustion
Model
According to the theory of combustion of pulverized coal in the
furnace, gas turbulent flow model is the realization k
-
ε (2 eqn) model.
Turbulent dispersion of coal particles uses discrete random walk
model, and devolatilization model is
t
h
e single
-rate. The char
combustion model is kinetics/diffusion
-limited, and the radiation heat
transfer is simulated by the P1 radiation model; turbulent flow
diffusion flame uses the Non
-Premixed combustion model
(Smoot
and Pratt, 1979
)
.
The pressure based solver is used to simulate the cold and hot
state of the boiler, and the patch button is used to initialize the
temperature field (2000K) for ignition. Firstly, the combustion in the
furnace is simulated, and the generation of NO
x is not considered.
Finally, the post processing method is used to calculate the NO
x
generation.
2.3.2 NO
x
Formation
Model
In the thermal power plant, the NO
x of the pulverized coal boiler is
mainly NO and NO
2. The content of NO is 95% (volume
concentration) of total NO
x. So the calculation mainly consider the
generation of NO, which can be converted into NO
x through
conversion relations. The generation of NO
x is based on the PDF
transport equation model. NO
x is divided into thermal NO
x, fuel NO
x
and prompt NO
x
. And prompt NO
x is less in pulverized coal boiler,
so it is neglected
.
Fig.
2 Grid division in the furnace
Fig.
3 Air distribution of burner
s
(b) AirJetTM
Center air
Pri
mary air
Internal secondary
air
External secondary air
(a) DRB
-4ZTM
Primary
air
Transition air
Internal secondary air
External secondary
air
Page 3 of 8
Frontiers in Heat and Mass Transfer (FHMT), 8, 3 (2017)
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Thermal NO
x is the oxidation product of
N
2 in air at high
temperature. And its formation process is a no branch chain reaction,
mainly affected by temperature, with its formation mechanism
represented by Zeldovich reactio
n
(Hill and Smoot, 2000
). Reaction 1
is the decomposition of nitrogen, due to the decomposition of the
required activation energy is relatively large, so the reaction must be
carried out at high temperature. The speed of the whole chain
reaction is mainly determined by the slowest reaction type 1.
1
1
2
kk
N O N NO
(1) 22
2
kk
O N NO O
(2) 33 kk
OH N NO H
(3)
The fuel NO
x reaction is relatively complex, using the De Soete
mode
l
(Soete, 1975)
, and its formation is divided into two parts, the
oxidation of volatile N and the oxidation of char N, as shown in
Figure
4. The intermediate product of volatile N to NO is HCN and
NH
i. Char N is directly oxidized to NO
x. And a part of NO
x can be
reduced into N
2
.
3. RESULTS AND
D
I
S
C
U
S
S
I
O
N
S
3.1 Effect of SOFA on NO
x
The analysis of the boiler operating conditions is 270MW, and the
total air volume and total amount of coal remain unchanged.
Conditions of six different ratios of SOFA are numerically simulated
by adjusting the air ratio.
Analyze NO
x yield under different SOFA
ratios
(NO
x yield under 6% oxygen content). NO
x distribution is
shown in
Figure 5. 0 10 20 30 40 0
50
100
150
200
250
300 NOx /mgm-3
High /m
26.02%
30.95%
33.48%
34.98%
36.02%
38.48%
Fig.
5 The NO
x distribution of different SOFA condition
s
It can be seen from the figure that the air staged combustion is
beneficial to reduce the NO
x production in the main combustion zone.
Only in the vicinity of the burner NO
x production is slightly higher,
the other region is in a better reducing atmosphere, is not conducive
to the production of NO
x
. And the yield of NO
x and SOFA ratios
have a great relationship. It is not true that the more SOFA ratio, the
better air staged combustion, and the less NO
x emissions. This is due
to the input of SOFA through nozzles which have destroyed the
reductive environment, and supply a large amount of air for coal
combustion, and NO
x production begin to increase. If it doesn
’
t
reasonably control the output of this area NO
x, even if the main fuel
area NO
x production is very low, still makes the furnace outlet NO
x
production is very large. Considering the change of the whole furnace
production of NO
x can be seen that with SOFA from less to more, the
NO
x production of furnace outlet decreased first and then increased.
For the boiler in 270MW load, when the SOFA ratio is 34.98%, the
yield of NO
x is minimum. So select the optimal working conditions
as the research object, through the study of the distribution of NO
x,
analysis of the generation mechanism of NO
x
.
3.2 Distribution of
Thermal NO
x
Figure 6 is the distribution of temperature and thermal NO in the
longitudinal section of the furnace (z=6.9). It can be clearly seen that
the distribution of thermal NO is similar to temperature. In the high
temperature region of the furnace, it is conducive to the generation of
thermal NO. In the lower temperature zone, the thermal NO
production is also less, just according with the formation mechanism
of the thermal type NO.
And it can be seen from the figure, in addition to the high
temperature region in the main combustion zone will produce a large
amount of thermal NO, in the burnout zone because of SOFA input,
making unburned coal combustion in the region area, the temperature
increased, it is accompanied by generation of a part of thermal NO.
In order to further analyze the law of thermal NO, this paper
also takes the section average value of thermal NO generation rate,
temperature, oxygen and CO along the height of furnace, as shown in figure 7 and 8.
From the change curve of the section average of thermal NO it
can be seen that its change trend is very similar with oxygen, and
from Zeldovich mechanism, it is found that the formation of thermal NO is not only related to temperature, but also influenced by oxygen.
NO
O
2
N
2
Char
Fig.
4
Formation mechanism of fuel NO
x
N
O
N
2
Volatile N
Char N
HCN
、NHi
O
2
Fig.
6 The distribution of temperature (K) and thermal NO
(
μL/L) in the longitudinal section of the furnace (z=6.9)
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In the main combustion zone, the formation rate of thermal NO
has been decreased two times. Because the air staged combustion to
make this area as a whole is in negative oxygen combustion. The
oxygen content is relatively high in the vicinity of burners, and in
other areas oxygen content is very low. Therefore, the thermal NO
decreased with the decrease of the oxygen content of two times. It
can be seen that in the high temperature region, the formation of
thermal NO is also affected by oxygen. When the oxygen is sufficient,
thermal NO can be produced in a large amount; when the oxygen is
insufficient, even if the temperature is appropriate, there will not be
thermal NO formation. 0 10 20 30 40
0.0
4.0x10-8 8.0x10-8 1.2x10-7 1.6x10-7 2.0x10-7 Thermal NO Rate Temperature
High /m Thermal NO Rate /kgmolm-3s-1
1100
1200
1300
1400
1500
1600 Temperature /K
Fig.
7
The section average value of thermal NO rate, temperature 0 10 20 30 40 0246 O2 CO
High /m O2 /% 0369
12
15 CO /%
Fig.
8
The section average value of
O
2 and CO
At the height of 18.5 m, which is near the third layer burners,
the oxygen content increases, but the heat type NO generation rate of
the area is not increased from figure 7. From figure 8 it can be seen
that the amount of CO in this area is very high, and form a strong
reducing state, which makes some thermodynamic NO is reduced,
and is not conducive to the oxidation of N. Therefore, the region's
thermal NO generation rate is very small.
At about the height of 25m, which is near the SOFA nozzle,
because the cooling effect of SOFA, temperature decreased firstly,
then with the unburned pulverized coal burning in sufficient oxygen,
the temperature increased rapidly. But the change curve of the
thermal NO generation rate was obviously increased at the lowest
temperature. From figure 8 it can be seen that its change trend is very
similar with oxygen. The three reaction of Zeldovich mechanism is
used to analyze, because the temperature of the main combustion
zone is relatively high, the reaction 1 is normally carried out, and the
nitrogen is decomposed to generate a part of N atoms. But because of
the relatively high amount of CO in the main combustion zone, the
whole is in a reduced state, which is not conducive to the reaction of
2 and 3. So there is a large amount of N atoms to be remained in the
main combustion zone. Due to the addition of SOFA, the oxygen
content increased, CO decreased, and N atoms was oxidized to
generate a large amount of NO by the reaction of 2 and 3 (reaction 2
and 3 don’t need high temperature). The change trend of the thermal
NO generation rate increases with the increase of oxygen in this
region, and it seems that the relationship with temperature is not very
big. In the vicinity of the Arch Nose, the thermal NO formation rate
also had a small fluctuation. Because the bending angle makes the
temperature of the partial area is higher.
Under the condition of the boiler, the temperature in the furnace
is not very high (below 1500
°
C), which is not conducive to the
formation of thermal NO
x. So the thermal NO
x production in this
boiler is relatively small, only about 12% of the total NO
x yield.
3.3 Distribution of
Fuel NO
x
3.3.1 Distribution of Volatile NO
From the formation mechanism of fuel NO
x in figure 4, fuel NO is
divided into two parts, the oxidation of volatile N and the oxidation
of char N, as shown in
figure
4. In this paper, try to simulate the
formation of these parts separately, so as to analyze the distribution
of NO in a qualitative way. Among them, with the precipitation of
volatile, volatile
N was quickly oxidized into NO. The whole process
mainly occurs near the burners in the main combustion zone, as
shown in
Figure 9.
Fig.
9 The distribution of volatile NO
From the volatile NO distribution of the cross section
s of the
first layer and the second layer of the burner
s can be seen, these two
distribution
s are significantly different. The first layer is DRB
-4ZTM
burner
s. From inside to outside there are 4 channels, which are
respectively primary air, transition air, internal secondary air and
external secondary air. Pulverized coal with primary air enters the
furnace. Volatile evaporates in the outside of the primary air, and the
volatile N is also immediately oxidized to NO. So in the center area
volatile NO is little and in the outer region a large amount of volatile
NO will be product. The second layer is the AirJetTM burners. From
inside to outside there are 4 channels, which is respectively center air,
primary air, internal secondary air
, and external secondary air.
(c) Cross section of the second
layer burner
s
(b) Cross section of the first
layer burner
s
(a) Longitudinal section of furnace (Z=5.4375)
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Volatile evaporates in the outside of the primary air with a large
amount of volatile NO formation. So it can be seen from the figure C,
volatile NO mainly generated in the region of center air and
secondary air. Yield is less in the region of primary air.
3.3.2 Distribution of Char NO
Fig. 10 The distribution of char NO (Z=5.4375) 0 10 20 30 40
0.0
5.0x10-6
1.0x10-5 Char NO Rate DPM Burnout
High /m Char NO Rate /kgmolm-3s-1
0.0
2.0x10-5
4.0x10-5 DPM Burnout /kgs-1
Fig. 11 The section average value of char NO rate and char
combustion rate
Figure
s 10 and 11 show the distribution of char NO in the furnace
(Z=5.4375 m), and the section average value of char NO formation
rate and char combustion rate along the furnace height.
From the figure it can be clearly seen that a large amount of the
char NO generated in the hopper area, the main combustion zone and
burnout zone. And the law of its production is almost identical with
the combustion of coke. The combustion process of coke is
accompanied with the production of char NO. Due to the air staged,
the formation rate of NO was higher near the first and two layer
burners in the main combustion zone. Then due to the insufficient
oxygen and more CO, reducing state is better, resulting in a reduction
of the rate of char NO, and some NO is reduced.
From figure 11 it can be seen that in the burnout zone because of
the SOFA input, unburned char began to burn fully, it is also
accompanied by the generation of a large amount of char NO. So
oxygen has a great influence on the formation of char NO.
3.3.3 Production
Law of
Fuel NO
From the formation mechanism of fuel NO
x in figure 4, during the
actual generation of fuel NO, the volatile NO and char NO are
mutually influenced, especially the intermediate product HCN and
NHi when the volatile N is converted to NO, which has a great
influence on the reduction of the char NO. The above methods can
only be qualitative analysis of the distribution of the law, and can
n
o
t
reflect the real law of fuel NO
x
.
It is still necessary to overall analysis
of the various factors affecting the fuel NO
x
. 0 10 20 30 40
-1.50x10-6 0.00
1.50x10-6 3.00x10-6 4.50x10-6 6.00x10-6 7.50x10-6 Fuel NO Rate O2
High /m Fuel NO Rate /kgmolm-3s-1 02468 O2 /%
Fig. 12 The section average value of fuel NO rate and O
2 0 10 20 30 40 0
30
60
90
120
150 Fuel NO
CO
High /m Fuel NO /L/L 0369
12 CO/%
Fig. 13 The section average value of fuel NO and CO
Figure 12 and 13 are the distribution of
O
2 and CO and fuel NO
in each section of the furnace. It can be seen that the combustion is
weak in hopper area duo to less oxygen, and a large amount of CO is
generate
d, and fuel NO production is very small. The formation rate
of the fuel NO is even negative, which shows that the NO diffused
from the main combustion zone is reduced here.
Around the first layer and the second layer of the burners in the
main combustion zone, due to the input of coal and adequate oxygen, the volatile is volatilized and rapid combustion, while some char is
burned. So a large amount of volatile NO and char NO generated, the
total fuel NO generation rate is very large. Between these two layers
of burners, the amount of oxygen is consumed, which is not
conducive to the formation of NO. And the amount of CO is more, so
the reduction is strong, and the generated NO is reduced. The yield of
fuel NO is decreased, and the production rate of fuel NO in some
areas is negative.
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In the vicinity of the third layer burner, only a small amount of
oxygen is put into furnace, and no coal. Although the oxygen content
increased, but the amount of CO is still very high, is not conducive to
the formation of NO. Therefore, the production of fuel NO is very
small in this vicinity
.
In the burnout zone, due to the inputs of SOFA,
the oxygen
content increased rapidly, CO was rapidly oxidized, so the amount of
CO decreased rapidly. In the main combustion zone due to lack of
oxygen, pulverized coal combustion is not fully, which can be fully
burned in the burned zone, and accompanied by a small amount of
volatile NO and a lot of char NO
.
3.4 The
Effect of the
Distribution of
Oxygen in the
Main
Combustion
Zone on NO
x
Table 2 Air distribution parameters and NO
x output of furnace outlet
Case 1 Case 2 Case 3
The ratio of primary air
%
21.54 21.54 21.54
The ratio of SOFA
%
34.98 34.98 34.98
The secondary air ratio of the first layer
%
18.22 20.00 16.50
The secondary air ratio of the second layer
%
18.74 16.96 20.46
The secondary air ratio of the third layer /% 6.52 6.52 6.52
NO
x output of furnace outlet /mg·Nm
-
3 215.23 231.56 217.78
Keep the total air volume, total amount of coal and primary air are
the same. When the SOFA ratio is 34.98%, by adjusting the
secondary air ratio of the first and second layer of burners, analyse
the effect of the distribution of oxygen in the main combustion zone
on the thermal NO
x and fuel NO
x. Specific distribution of air and
NO
x output of furnace outlet are shown in
Table 2: 0 10 20 30 40
1100
1200
1300
1400
1500
1600 Temperature /K
High /m
Case 1
Case 2
Case 3
Fig.
1
4 The section average value of temperature 0 10 20 30 40
0.0
5.0x10-8 1.0x10-7 1.5x10-7 2.0x10-7 2.5x10-7 Thermal NO Rate /kgmolm-3s-1
High /m
Case 1
Case 2
Case 3
Fig.
1
5 The section average value of thermal NO rat
e
Figure 14 is
the section average value of temperature with the
furnace height under these three conditions. It can be seen from the
figure, as compared with the other two conditions
, case
3 input more
secondary air through the second layer burner
s, and case 3 has a
relatively high temperature in the main combustion zone and burnout
zone, so the thermal NO yield is relatively high. It can be seen clearly
from the generation rate of thermal NO in
figure 15, and the thermal
NO rate in working condition 3 is relatively large
r. But the thermal
NO is relatively small for total NO yield, and the temperature
difference between these three conditions is not very large, the
thermal NO rate is also in the same order of magnitude, so the three
conditions of the heat type NO production is not large. Therefore,
there is only a little of difference of thermal NO production among
these three kinds of operating. The thermal NO can only be used as
reference, and the decisive factor is the fuel NO.
And from the distribution of oxygen in figure 16 can be seen
that, under the air staged combustion only near the burner oxygen is
more in main combustion zone,
so the thermal NO is only generated
in the vicinity of the burner
s
. Less oxygen place, heat type NO
production is also less, just to verify the previous theory that
thermal
NO can only be produced at high temperature, and it is affected by
oxygen. 0 10 20 30 40 0246O2 /%
High /m
Case 1
Case 2
Case 3
Fig.
1
6 The section average value of fuel
O
2 0 10 20 30 40 0369
12 CO /%
High /m
Case 1
Case 2
Case 3
Fig.
1
7 The section average value of fuel CO
Figure 1
6 is the section average value of
O
2 with the furnace
height under these three conditions. As can be seen from the
distribution of
O
2, because of case 2 inputting most air in the first
layer burners, the oxygen content around the first layer of burner
s is
the highest. And because of case 3 inputting most air in the second
layer burners, the oxygen content around the second layer of burner
s
is the highest. From the previous analysis of fuel NO that the
formation of fuel NO is proportional to the amount of oxygen, case 2
around the first layer burner
s generated more fuel NO, and case 3
around the second layer burner
s generate
d more fuel NO, as shown in
Figure 18
.
Page 7 of 8
Frontiers in Heat and Mass Transfer (FHMT), 8, 3 (2017)
DOI: 10.5098/hmt.8.3
Global Digital Central
ISSN: 2151-8629
7
Comprehensive analysis of the fuel type NO formation factors
and reduction factors, it is not difficult to get out, case 2 due to the
worst
reducibility, so that the furnace outlet NO
x production is
relatively more. In order to reduce NO
x emissions at furnace exit, the
distribution of oxygen in the main combustion zone must be
reasonable based on the control of the SOFA ratio. The first layer of
the air flow can
n
o
t be too much, in order to enable the main
combustion zone form a good
reducibility, reducing the NO
x
production. 5 10 15 20 25 30 35
0.0
2.0x10-6
4.0x10-6
6.0x10-6 Fuel NO Rate /kg×mol×m-3×s-1
High /m
Case 1 Case 2 Case 3
Fig.
1
8 The section average value of fuel NO rat
e
4. CONCLUSION
S
The
fo
r
m
a
t
i
o
n of thermal NO and fuel type NO emission under the
air staged combustion in a tower pulverized coal fired boiler
i
s
a
n
a
l
y
z
e
d
. Based on the detailed analysis, the following conclusions
can be drawn:
(1) Air staged combustion is beneficial to reduce the NO
x output
of the main combustion zone, so as to reduce the NO
x
emission from the furnace outlet. There is an optimal value of
SOFA ratio, and the yield of NO
x under this condition is the
minimum.
(2) Thermal NO can only be produced at high temperature, and it
is affected by oxygen. When the oxygen is sufficient under
high temperature, thermal NO can be produced in a large
amount; when the oxygen is insufficient, even if the
temperature is appropriate, there will not be thermal NO
formation.
(3) The volatile matter of NO is mainly near the burners in the
main combustion zone. If air supply mode of burner is
different, the distribution of volatile NO is also slightly
different.
(4) The oxidation of char N is closely related to oxygen, and is
affected by CO. The more oxygen, the more char NO
production. When the amount of CO is more, some char NO
will be reduced.
(5) A large amount of fuel NO will be generated near the burners
in the main combustion zone. But the main combustion zone
is in the negative oxygen combustion, a lot of generated NO is
reduced. In the burnout zone due to unburned pulverized coal
burning again, a large amount of fuel NO will be produced.
(6) In order to reduce NO
x emissions at furnace exit, the
distribution of oxygen in the main combustion zone must be
reasonable based on the control of the SOFA ratio. The first
layer of the air flow can
n
ot be too
h
i
g
h, in order to enable the
main combustion zone form a good reducibility, reducing the
NO
x production.
ACKNOWLEDGEMENTS
This work was financially supported by National Natural Science
Foundation of China (No. 51476103), Public welfare scientific
research projects of Shanghai Municipal Bureau of Quality and
Technical Supervision (No. 2012
-41), Innovation Program of
Shanghai Municipal Education Commission (No. 14ZZ134) and
Shanghai Pujiang Program (No. 14PJ1407000).
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